Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl]iminomethyl}phenolato)copper(II) dihydrate
نویسندگان
چکیده
In the title compound, [Cu(C(12)H(16)NO(5))(2)]·2H(2)O, the Cu(II) ion adopts a trans-CuN(2)O(4) octa-hedral geometry arising from two N,O,O'-tridentate 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]-imino-meth-yl}phenolate ligands. The Jahn-Teller distortion of the copper centre is unusally small. In the crystal structure, O-H⋯O hydrogen bonds, some of which are bifurcated, link the component species.
منابع مشابه
Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl-κO]iminomethyl}phenolato-κ2 N,O 1)nickel(II) dihydrate
In the title compound, [Ni(C(12)H(16)NO(5))(2)]·2H(2)O, the Ni(II) atom is coordinated by four O atoms and two N atoms from the two 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]imino-meth-yl}phenolate ligands in a distorted octa-hedral coordination geometry. O-H⋯O hydrogen bonds link the complexes and uncoordinated water mol-ecules into two-dimensional networks parallel to (001).
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009